In a First Song I Ever Heard By This Band or Soloist category, I'll give you something from Jethro Tull. The first thing I ever heard from Ian Anderson was Living In The Past, although, as it was buried within the soundtrack of a documentary, I had absolutely no idea who it was. So the first thing I heard from Tull and knew it was Life's A Long Song.
A couple of years ago I stumbled over a series where Rick Wakeman was talking to fellow musicians. The chat with Ian Anderson was particularly interesting. In it, Rick asked Ian why he took up the flute. Anderson's reply was amazing. He said that, although he was a guitarist, he'd recently seen Jimi Hendrix blow everyone else away, and so he decided that being a guitarist wasn't enough. He had to have a new angle. So he saw a flute in a music shop and decided to buy it. He taught himself within 6 months to virtuosity, although he still denies that he is any good.! Anyway, he plays the acoustic guitar very prettilly in this one:
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Still my favourite Tull song, just perfect.

